Dichlorido[1-(1,10-phenanthrolin-2-yl)-2-pyridone]cadmium(II)
نویسندگان
چکیده
منابع مشابه
Dichlorido[1-(1,10-phenanthrolin-2-yl)-2-pyridone]copper(II)
In the title mononuclear complex, [CuCl(2)(C(17)H(11)N(3)O)], the Cu(II) ion is in a distorted square-pyramidal coordination environment. The crystal structure is stabilized by various π-π stacking inter-actions in which the benzene ring, a pyridine ring and the five-membered CuN(2)C(2) ring are involved. The centroid-centroid distances range from 3.5631 (15) to 3.5666 (16) Å.
متن کاملDichlorido[1-(1,10-phenanthrolin-2-yl)-2-pyridone]cadmium(II)
In the title mononuclear complex, [CdCl(2)(C(17)H(11)N(3)O)], the Cd(II) ion assumes a distorted trigonal-bipyramidal coordination geometry. The pyridone plane is twisted out of the 1,10-phenanthroline mean plane by 43.8 (3)°. In the crystal structure, short inter-molecular distances [3.627 (4)-3.671 (4) Å] between the centroids of the six- and five-membered Cd-containing rings suggest the exis...
متن کاملN-(1,10-Phenanthrolin-5-yl)-4-(2-pyridyl)benzamide monohydrate
In the title mol-ecule, C(24)H(16)N(4)O·H(2)O, the benzene ring of the 1,10-phenanthroline group and that of the 2-phenyl-pyridine group are respectively twisted by 67.9 (1) and 15.3 (3)° from the carbamoyl group defined by the plane of the O=C-N group of atoms. The water mol-ecule is hydrogen bonded to one of the phenanthroline N atoms. In the crystal structure, significant π-π stacking inter-...
متن کامل2-[(E)-(1,10-Phenanthrolin-5-yl)iminomethyl]phenol methanol monosolvate
In the title multi-donor Schiff base compound, C(19)H(13)N(3)O·CH(3)OH, the dihedral angle between the mean planes of the phenanthroline and phenol rings is 59.3 (1)°. The Schiff base mol-ecule is linked to the solvent mol-ecule by an O-H⋯O hydrogen bond. In the crystal, the components are linked by O-H⋯N hydrogen bonds, weak O-H⋯N inter-actions and π-π stacking inter-actions [centroid-centroid...
متن کاملPerchloratobis[1-(1,10-phenanthrolin-2-yl)-2-pyridone]zinc(II) perchlorate
In the title mononuclear complex, [Zn(ClO(4))(C(17)H(11)N(3)O)(2)]ClO(4), the Zn(II) ion is coordinated in a distorted octa-hedral geometry. The dihedral angles between the pyridine rings and the mean planes of the 1,10-phenanthroline ring system in each of the 1-(1,10-phenanthrolin-2-yl)-2-pyridone (PP) ligands is 24.51 (10)° for the tridendate PP ligand and 73.55 (6)° for the bidentate PP lig...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808019740